Structure, stability, persistence, and reactions of organic free radicals; common chain and non-chain radical reactions; mechanisms of initiation, propagation and termination; methods of studying the kinetics of radical reactions; common radical reactions in organic synthesis and applications in natural product synthesis; radicals in biology: lipid peroxidation, radical-trapping antioxidants, radical-based enzymes. Not offered 2010-2011.
Structure, stability, persistence, and reactions of organic free radicals; common chain and non-chain radical reactions; mechanisms of initiation, propagation and termination; methods of studying the kinetics of radical reactions; common radical reactions in organic synthesis and applications in natural product synthesis; radicals in biology: lipid peroxidation, radical-trapping antioxidants, radical-based enzymes. Not offered 2010-2011.