Students are introduced to the varied aspects of transition metal chemistry and a wide variety of techniques which have been applied to these systems. Topics include coordination numbers, stereochemistry, diastereomers, enantiomers, coordination equilibria, and the kinetics and mechanisms of substitution and electron transfer reactions. Crystal field and molecular orbital descriptions of bonding are developed and applied to electronic spectra and magnetic properties. Application to some bioinorganic systems are introduced. Prerequisite: CHEM 2160/2250 (C- minimum)
Students are introduced to the varied aspects of transition metal chemistry and a wide variety of techniques which have been applied to these systems. Topics include coordination numbers, stereochemistry, diastereomers, enantiomers, coordination equilibria, and the kinetics and mechanisms of substitution and electron transfer reactions. Crystal field and molecular orbital descriptions of bonding are developed and applied to electronic spectra and magnetic properties. Application to some bioinorganic systems are introduced. Prerequisite: CHEM 2160/2250 (C- minimum)
